The free hydroxyl groups may be present as polyhydric alcohols, partial esters, polyester end groups or hydroxylated fatty acids. The method of test is not applicable to resin containing both hydroxyl groups and epoxide groups, because the latter will also be attacked and included in the result. The principle consists in acetylation of the groups with anhydride, hydrolysis of the exess acetic anhydride and titration of the resulting acetic acid with potassium hydroxide solution, either in the presence of a colour indicator or potentiometrically. The method is not applicable to cellulose nitrate or phenolic resins.
Số hiệu tiêu chuẩn
ISO 4629
Tên tiêu chuẩn
Paint media; Determination of hydroxyl value; Titrimetric method
Ngày phát hành
1978-11-00
Tiêu chuẩn tương đương
DIN ISO 4629 (1979-11), IDT * BS 6782-4 (1987-03-31), IDT * NF T30-403 (1976-04-01), MOD * ELOT 577 (1986), IDT * NP-2054, IDT
Từ khóa
Acetic acid * Alcohols * Ambient temperatures * Analysis * Binding agents * Burettes * Butanol * Chemical analysis and testing * Coating materials * Colour indicator * Conical flasks * Coolers * Definitions * Determination of content * Esters * Ethyl acetate * Ethylene acetate * Fatty acids * Hydrolysis * Hydroxyl value * Instruments * Mathematical calculations * Mixtures * Paints * Pipettes * Pyridine * Reflux * Sample portions * Samples * Temperature * Test reports * Test standards * Testing * Titration * Titrimetry * Tolerances (measurement) * Toluene * Varnishes * Volumetric analysis